Hey man, thanks for your replies.
1. I'll keep it on van then. I wasn't planning on using the car battery for anything except the car. Although it wouldn't be the end of the world - I have a lithium ion battery pack that jump starts my van from cold, without the battery even being disconnected! I started the van 3 times and the battery indicator didn't even go down! Even so, I won't be using the car battery.
2 & 4 - That makes sense, I hadn't thought of the power going through the switch! Obviously that's not happening, and now you mention it, I'm pretty sure these shore power hookup points charge directly into the leisure battery. As for charging while driving, I do vaguely remember the owner saying something about the leisure batteries being charged when driving, I just don't remember what as I had so much new information at the time!
2. Fridge is an electrolux RM 2262, which is a 3 way fridge - gas, 12v and mains. Takes about 0.25 kg per 24 hours according to the manual, so on the off chance I do need to use the fridge - the big 12kg gas bottle I have will do the trick!
3. Mains is currently connected by the standard 230V hookup to the van, then I have an adaptor I bought off ebay, that connects to the hookup and plugs into a standard plug socket.