At night get engine up to temp and then search round with a good torch. You may have a leak under pressure that evaporates and leaves no trace.
Also check pressure cap is ok, and that the pick up hose inside the expansion bottle does not collapse on itself.
Lastly and I hope not but you may have a cracked head, best way to check is start the engine and then quickly remove the pressure cap, If you have loads of bubbles then sadly that is a cracked head.